Hello Abercrombie1963,
I see that you want to know how to unsync your devices. I'd be happy to provide you with some information that can help.
Manage Alexa Devices Mac Address
If you're just trying to unsync devices that are all yours and not other family members, you can just sign out of the devices that you do not want to sync anymore.
Manage Alexa Devices Mac 10
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Use Alexa On Mac
Sign out of iCloud on your iPhone, iPad, iPod touch, Apple TV, or Mac
If you're sharing an Apple ID with a family member or members, you'd want to create separate Apple ID's for everyone and then you could set up Family Sharing, to be able to have access to any purchases that were made with that Apple ID.
Create an Apple ID
Set up Family Sharing
If neither of these is what you're trying to do, reply back with some more details.
Reformat mac hdd. Have a great day!